Lucario

Lucario is a character in the Pokémon series. It is set to appear in the 80th episode Lucario VS Renamon, where it'll face off against it's rival Renamon.

One Minute Melee
Lucario also appeared in One Minute Melee, where it fought it's rival Renamon, which ended in a draw.

DBX
Lucario also appeared in a DBX episode, where it fought Ryu from the Street Fighter series. He ended up losing, and caught in by Ryu in his Pokémon Go app.